Not really,
As per the Univ of Virginia website
"Aside from a complete medical history and physical and pelvic examination, diagnostic procedures for PMS are currently very limited. Your physician may consider recommending a psychiatric evaluation to, more or less, provide a differential diagnosis (to rule out other possible conditions). In addition, he/she may ask that you keep a journal or diary of your symptoms for several months, to better assess the timing, severity, onset, and duration of symptoms."
You can take a print out to try to convince your doctor about this possibility,
Also the good news is that you can try the treatment options mentioned in consultation with your physician and see if they work,
Some of the treatment options are OTC and hence can be tried even without a prescription,
All the best,
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Regards
Dr. Gupta